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According to Pliny the Elder, Phoenician traders were the first to stumble upon glass manufacturing techniques at the site of the Belus River.Georgius Agricola, in De re metallica, reported a traditional serendipitous "discovery" tale of familiar type: "The tradition is that a merchant ship laden with nitrum being moored at this place, the merchants were preparing their meal on the beach, and not having stones to prop up their pots, they used lumps of nitrum from the ship, which fused and mixed with the sands of the shore, and there flowed streams of a new translucent liquid, and thus was the origin of glass." This account is more a reflection of Roman experience of glass production, however, as white silica sand from this area was used in the production of glass within the Roman Empire due to its high purity levels.Glass shapes for inlays were also often created in moulds.Much early glass production, however, relied on grinding techniques borrowed from stone working.

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But in general, archaeological evidence suggests that the first true glass was made in coastal north Syria, Mesopotamia or ancient Egypt.Because of Egypt's favorable environment for preservation, the majority of well-studied early glass is found there, although some of this is likely to have been imported.The earliest known glass objects, of the mid third millennium BC, were beads, perhaps initially created as accidental by-products of metal-working (slags) or during the production of faience, a pre-glass vitreous material made by a process similar to glazing.The history of glass-making can be traced back to 3500 BCE Asia in Mesopotamia, however, they may have been producing second-rate copies of glass objects from Egypt, where this complex craft actually originated.The earliest known glass objects, of the mid second millennium BC, were beads, perhaps initially created as the accidental by-products of metal-working (slags) or during the production of faience, a pre-glass vitreous material made by a process similar to glazing.In ancient China, though, glass-making seems to have had a late start compared to ceramics and metal work.